Two-Dimensional Carbon Compounds Derived from Graphyne with Chemical Properties Superior to Those of Graphene
نویسندگان
چکیده
منابع مشابه
Two-Dimensional Carbon Compounds Derived from Graphyne with Chemical Properties Superior to Those of Graphene
Computational studies considering both thermodynamic and kinetic aspects revealed that graphyne, a carbon material that has recently been of increasing interest, favours unprecedented homogeneous "in-plane" addition reactions. The addition of dichlorocarbene to the C(sp)-C(sp) bond, a site with outstanding regioselectivity in graphyne, proceeds via a stepwise mechanism. Due to their homogeneous...
متن کاملTwo-dimensional carbon topological insulators superior to graphene
Graphene was the first material predicted to realize a topological insulator (TI), but unfortunately the gap is unobservably small due to carbon's weak spin-orbital coupling (SOC). Based on first-principles calculations, we propose a stable sp-sp(2) hybrid carbon network as a graphene analog whose electronic band structures in proximity of the Fermi level are characterized by Dirac cones. We de...
متن کاملTwo dimensional Dirac carbon allotropes from graphene.
Using a structural search method in combination with first-principles calculations, we found lots of low energy 2D carbon allotropes and examined all possible Dirac points around their Fermi levels. Three amazing 2D Dirac carbon allotropes have been discovered, named as S-graphene, D-graphene and E-graphene. By analyzing the topology correlations among S-, T, net W graphene and graphene, we fou...
متن کاملFrom point defects in graphene to two-dimensional amorphous carbon.
While crystalline two-dimensional materials have become an experimental reality during the past few years, an amorphous 2D material has not been reported before. Here, using electron irradiation we create an sp2-hybridized one-atom-thick flat carbon membrane with a random arrangement of polygons, including four-membered carbon rings. We show how the transformation occurs step by step by nucleat...
متن کاملEvolving properties of two-dimensional materials: from graphene to graphite.
We have studied theoretically, using density functional theory, several material properties when going from one C layer in graphene to two and three graphene layers and on to graphite. The properties we have focused on are the elastic constants, electronic structure (energy bands and density of states), and the dielectric properties. For any of the properties we have investigated the modificati...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Scientific Reports
سال: 2013
ISSN: 2045-2322
DOI: 10.1038/srep01271